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Mineralogy & Geochemistry Laboratories Thermal analysis Isoperiboles thermal conductivity calorimeter

Calorimetry: Isoperiboles thermal conductivity calorimeter

Endothermic and exothermic reactions are measured in difference to an inert reference. The thermoelectric voltage, which is proportional to the heat flow of the respective sample, serves as the measurement signal. The heat of reaction can be measured via the integral of the temperature differences as a function of time. Thermal conductivity calorimetry is used for precise quantitative measurements of heats of reaction or for the qualitative visualisation of hydration processes.

  • Quantitative determination of reaction heats
  • Hydration reactions as a function of the specific surface area
  • Quality control of cement clinkers and cements
  • Temperature influences on hydration (isoperibolic mode)
  • Special properties of alumina cements
  • Investigation and influence of additives and aggregates
  • Lime hydration and carbonation reactions
  • Polymerisation of glasses
  • Carbonation reactions of cements and mortars

Left: Isoperiboles ‍heat flow calorimeter ‍with ‍hot additive
Right: Calorimeter: ‍Aluminium block ‍with ‍3 ‍measuring stations ‍and ‍reference

Areas of application

  • Quantitative determination of reaction heats
  • Hydration reactions as a function of the specific surface area
  • Quality control of cement clinkers and cements
  • Temperature influences on hydration (isoperibolic mode)
  • Special properties of alumina cements
  • Investigation and influence of additives and aggregates
  • Lime hydration and carbonation reactions
  • Polymerisation of glasses
  • Carbonation reactions of cements and mortars
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